Evaporation from Nanoporous Membranes

Cooling demands of advanced electronics are increasing rapidly, often exceeding capabilities of conventional thermal management techniques. Thin film evaporation has emerged as one of the most promising thermal management solutions. High heat transfer rates can be achieved in thin films of liquids due to a small conduction resistance through the film to the evaporating interface. In this thesis, we investigated evaporation from nanoporous membranes. The capillary wicking of the nanopores supplies liquid to the evaporating interface, passively maintaining the thin film. Different evaporation regimes were predicted through modeling and were demonstrated experimentally. Good agreement was shown between the predicted and observed transitions between regimes. Improved heat transfer performance was demonstrated in the pore level evaporation regime over other regimes, with heat transfer rates up to one order of magnitude larger for a given superheat in comparison to the flooding regime. An improved experimental setup for investigating thin film evaporation from nanopores was developed, where a biphilic membrane, i.e., a membrane with two wetting behaviors, was used for enhanced experimental control to allow characterization of the importance of different design parameters. This improved setup was then used to demonstrate the dependence of thin film evaporation on the location of the meniscus within the nanopores. This dependence on meniscus location within the pore was also shown to increase with increasing superheat. We observed a 46% reduction in heat transfer rates at a superheat of 15 "C for an L* of 14.67 compared to an L* of 2, where L* is the ratio of the depth of the meniscus within the pore to the pore radius.